Structure Board is a full-screen view with the structure widget and without anything else, so it's good for focusing your work on the structure.

Structure Board is opened when you click on the Structure top navigation menu in JIRA.

You can press g and then quickly s on any JIRA page to open the structure board. (Go Structure)

If you have several structures in JIRA, clicking Structure top navigation menu opens the most recently used structure.

You can open a specific, not current structure on the structure board using any of the following options:

Structure Board will try to accomodate structure widget nicely on your browser page to take advantage of most of the available space.