If you want to go straight to the Structure Board when you log in to JIRA, you can make it your JIRA Home page. To do so:
When used as a JIRA Home page, the Structure Board will show your current structure, as if you clicked the top-level Structure menu.
You can also go to your JIRA Home at any time by clicking the JIRA logo in the top-left corner of any JIRA page.